This study characterizes the pool boiling performance of HFO-1234yf (hydrofluoroolefin 2,3,3,3-tetrafluoropropene). HFO-1234yf is a new, environmentally friendly refrigerant likely to replace HFC-134a in automotive air-conditioning systems. Pool boiling experiments were conducted at system pressures ranging from 0.7 to 1.7 MPa using horizontally oriented 1-cm2 heated surfaces. Test results for pure (oil-free) HFO-1234yf and HFC-134a were compared. The results showed that the boiling heat transfer coefficients of HFO-1234yf and HFC-134a were nearly identical at lower heat fluxes. HFO-1234yf yielded lower heat transfer coefficients at higher heat fluxes and lower critical heat flux (CHF) values as compared with HFC-134a. To enhance boiling heat transfer, a copper microporous coating was applied to the test surfaces. The coating enhanced both the boiling heat transfer coefficients and CHF for both refrigerants at all tested pressures. Increasing pressure decreased the level of heat transfer coefficient enhancements and increased the level of CHF enhancements. The experimental data were then used to develop a correlation for predicting the CHF for a smooth/plain heated surface.