The damage mechanisms of carbon nanotubes are considered to be the oxidation by Joule heating and migration of carbon atoms by high-density electron flows. In this study, a high current density testing system was designed and applied to multiwalled carbon nanotubes (MWCNTs) collected at the gap between thin-film electrodes. Local evaporation of carbon atoms occurred on the cathode side of the MWCNTs under relatively low current density conditions, and the center area of the MWCNTs under high current density conditions. The damaged morphology could be explained by considering both Joule heating and electromigration behavior of MWCNTs.

References

1.
Iijima
,
S.
,
1991
, “
Helical Microtubules of Graphitic Carbon
,”
Nature
,
354
(6348), pp.
56
58
.10.1038/354056a0
2.
Yokoyama
,
D.
,
Iwasaki
,
T.
,
Yoshida
,
T.
, and
Kawarada
,
H.
,
2007
, “
Low Temperature Grown Carbon Nanotube Interconnects Using Inner Shells by Chemical Mechanical Polishing
,”
Appl. Phys. Lett.
,
91
(26), p.
263101
.10.1063/1.2824390
3.
Yao
,
Z.
,
Kane
,
C. L.
, and
Dekker
,
C.
,
2000
, “
High-Field Electrical Transport in Single-Wall Carbon Nanotubes
,”
Phys. Rev. Lett.
,
84
(13), pp.
2941
2944
.10.1103/PhysRevLett.84.2941
4.
Begtrup
,
G. E.
,
Ray
,
K. G.
,
Kessler
B. M.
,
Yuzvinsky
,
T. D.
, and
Garcia
,
H.
,
2007
, “
Extreme Thermal Stability of Carbon Nanotubes
,”
Phys. Status Solidi B
,
244
(11), pp.
3960
3963
.10.1002/pssb.200776148
5.
Collins
,
P. G.
,
Arnold
,
M. S.
, and
Avouris
,
P.
,
2001
, “
Engineering Carbon Nanotubes and Nanotube Circuits Using Electrical Breakdown
,”
Science
,
292
(5517), pp.
706
709
.10.1126/science.1058782
6.
Tsang
,
S. C.
,
Harris
,
P. J. F.
, and
Green
,
M. L. H.
,
1993
, “
Thinning and Opening of Carbon Nanotubes by Oxidation Using Carbon Dioxide
,”
Nature
,
362
(6420), pp.
520
522
.10.1038/362520a0
7.
Yuzvinsky
,
T. D.
,
Mickelson
,
W.
,
Aloni
,
S.
,
Begtrup
,
G. E.
,
Kis
,
A.
, and
Zettl
,
A.
,
2006
, “
Shrinking a Carbon Nanotube
,”
Nano Lett.
,
6
(12), pp.
2718
2722
.10.1021/nl061671j
8.
Jin
,
C.
,
Suenaga
,
K.
, and
Iijima
,
S.
,
2008
, “
Plumbing Carbon Nanotubes
,”
Nat. Nanotechnol.
,
3
(1), pp.
17
21
.10.1038/nnano.2007.406
9.
Verma
,
R.
,
Bhattacharya
,
S.
, and
Mahapatra
,
S.
,
2012
, “
Theoretical Estimation of Electromigration in Metallic Carbon Nanotubes Considering Self-Heating Effect
,”
IEEE Trans. Electron Devices
,
59
(9), pp.
2476
2482
.10.1109/TED.2012.2202909
10.
Sasagawa
,
K.
,
Unuma
,
J.
, and
Abo
,
T.
,
2011
, “
Effect of Oxygen Concentration on Damage Mechanism of Carbon Nanotubes Under High Current Density
,”
ASME
Paper No. IPACK2011-52169.10.1115/IPACK2011-52169
11.
Seo
,
H. W.
,
Han
,
C. S.
,
Jang
,
W. S.
, and
Park
,
J.
,
2006
, “
Manipulation of Carbon Nanotubes and Nanowires
,”
Curr. Appl. Phys.
,
6
(S1), pp.
216
219
.10.1016/j.cap.2006.01.043
12.
Sasagawa
,
K.
, and
Fukushi
,
S.
,
2007
, “
Evaluation of Threshold Current Density of Electromigration Damage in Angled Bamboo Lines
,”
ASME
Paper No. IPACK2007-33237.10.1115/IPACK2007-33237
13.
Hasegawa
,
K.
,
Sasagawa
,
K.
,
Uno
,
S.
,
Saka
,
M.
, and
Abé
,
H.
,
2009
, “
Derivation of Film Characteristic Constants of Polycrystalline Line for Reliability Evaluation Against Electromigration Failure
,”
Mech. Mater.
,
41
(10), pp.
1090
1095
.10.1016/j.mechmat.2009.04.009
14.
Maruyama
,
H.
,
Ishibashi
,
T.
,
Hirahara
,
K.
, and
Nakayama
,
Y.
,
2010
, “
Carbon Nanotube Sharpening Using an Induced Electrical Current
,”
Appl. Phys. Express
,
3
(2), p.
025101
.10.1143/APEX.3.025101
15.
Ajayan
,
P. M.
,
Ebbesen
,
T. W.
,
Ichihashi
,
T.
,
Iijima
,
S.
,
Tanigaki
,
K.
, and
Hiura
,
H.
,
1993
, “
Opening Carbon Nanotubes With Oxygen and Implications for Filling
,”
Nature
,
362
(6420), pp.
522
525
.10.1038/362522a0
You do not currently have access to this content.