Abstract

Polyvinylchloride (PVC) insulated stereo speaker wire from a homicide case involving the strangulation of a child was received by the FBI Laboratory for analysis. A method utilizing gel permeation chromatography to analyze PVC wire insulation was developed which was capable of discriminating between different commercially available brands of wire insulation. Using this method, we were able not only to link the wire found at the crime scene with a source from a suspect's residence, but also to associate it with a particular commercial brand of wire. The analysis of this case sample and other brands of stereo speaker wire is described.

References

1.
Runyon
,
J. R.
, “
Differential Gel Permeation Chromatography for Quality Control
,”
Journal of Applied Polymer Science
 0021-8995, Vol.
28
,
1983
, pp.
559
-
566
.
2.
Dudek
,
J. A.
, “
Good Quality Control is in the Bag
,”
Plastics Engineering
,
07
1980
, pp.
32
-
34
.
3.
Cunningham
,
A. F.
,
Heathcote
,
C.
,
Hillman
,
D. E.
, and
Paul
,
J. I.
,
Gel Permeation Chromatography of Nitrocellulose
,
Materials Quality Assurance Directorate
,
Woolwich, UK
, pp.
173
-
196
.
4.
Haney
,
M. A.
and
Dark
,
W. A.
, “
A Reversed-Phase High Pressure Liquid Chromatographic Method for Analysis of Additives in Polyolefins
,”
Journal of Chromatographic Science
 0021-9665, Vol.
18
, No.
12
,
12
1980
, pp.
655
-
659
.
5.
Howard
,
J. M.
, “
Gel Permeation Chromatography and Polymer Additive Systems
,”
Journal of Chromatography
 0021-9673, Vol.
55
, No.
15
,
1971
, pp.
15
-
24
.
6.
Stinson
,
S. C.
, “
Additives Sales Buoyed by PVC Recovery
,”
Chemical and Engineering News
,
18
06
1984
, pp.
27
-
52
.
7.
Hagnauer
,
G. L.
and
Setton
,
I.
, “
Compositional Analysis of Epoxy Resin Formulations
,”
Journal of Liquid Chromatography
, Vol.
1
, No.
1
,
1978
, pp.
55
-
73
.
8.
Pekala
,
R. W.
and
Merill
,
E. W.
, “
GPC Analysis of a Complex Silicone Adhesive System
,”
American Laboratory
,
05
1983
, pp.
14
-
25
.
9.
Hagnauer
,
G. L.
, “
Analysis of Commercial Epoxies by HPLC and GPC
,”
Industrial Research and Development
,
04
1981
, pp.
128
-
133
.
10.
Sarkar
,
A. K.
and
Roy
,
D. M.
, “
A New Characterization Technique for Trimethylsilylated Products of Old Cement Pastes
,”
Cement and Concrete Research
 0008-8846, Vol.
9
, No.
3
,
1979
, pp.
343
-
352
.
11.
Spagnolo
,
F.
and
Malone
,
W. M.
, “
Quantitative Determination of Small Amounts of Toluene Diisocyanate Monomer in Urethane Adhesives by Gel Permeation Chromatography
,”
Journal of Chromatographic Science
 0021-9665, Vol.
14
, No.
2
,
02
1976
, pp.
52
-
56
.
12.
Ouano
,
A. C.
,
Dawson
,
B. L.
, and
Johnson
,
D. E.
, “
Characterization of P(MMA) and P(MMA/MAA) by Low Angle Laser Light Scattering Photometry, GPC, and Viscometry
,”
Chromatographic Science
, Vol.
8
,
Liquid Chromatographic Polymer Related Materials
,
1977
, pp.
1
-
9
.
13.
Wheals
,
B. B.
, “
High Performance Size Exclusion Chromatography on Microparticulate Silicas and its Application to Forensic Analysis
,”
Journal of Liquid Chromatography
, Vol.
2
, No.
1
,
1979
, pp.
91
-
110
.
14.
Ellis
,
R. A.
, “
Recent Applications of Gel Permeation Chromatography in the Paint Industry—Part 1
,”
Pigment and Resin Technology
,
04
1978
, pp.
4
-
10
.
15.
Ellis
,
R. A.
, “
Recent Applications of Gel Permeation Chromatography in the Paint Industry—Part 2
,”
Pigment and Resin Technology
,
05
1978
, pp.
4
-
17
.
16.
Jabarin
,
S. A.
and
Balduff
,
D. C.
, “
Gel Permeation Chromatography of Poly(ethylene Terephthalate)
,”
Journal of Liquid Chromatography
, Vol.
5
, No.
10
,
1982
, pp.
1825
-
1845
.
17.
Greinke
,
R. A.
and
O'Connor
,
L. H.
, “
Determination of Molecular Weight Distributions of Polymerized Petroleum Pitch by Gel Permeation Chromatography with Quinoline Eluent
,”
Analytical Chemistry
 0003-2700, Vol.
52
, No.
12
,
10
1980
, pp.
1877
-
1881
.
18.
Gillyon
,
E. C. P.
, “
An Improvement in the Use of Gel Permeation Chromatography in the Characterization of Crude Oils
,”
Chromatographic Newsletter
, Vol.
9
, No.
2
,
1981
, pp.
60
-
61
.
19.
Philip
,
C. V.
and
Anthony
,
R. G.
, “
Analysis of Petroleum Crude and Distillates by Gel Permeation Chromatography
,”
Org. Coat. Applied Polymer Science Proceedings
, Vol.
48
,
1983
, pp.
974
-
978
.
20.
Giddings
,
J. C.
, “
Analysis of Fundamental Obstacles to the Size Exclusion Chromatography of Polymers of Ultrahigh Molecular Weight
,” in
Advanced Chromatography
, Vol.
20
, New York,
1982
, pp.
217
-
258
.
21.
Letot
,
L.
,
Lesec
,
J.
, and
Quivoron
,
C.
, “
The Errors in the Treatment of Gel Permeation Chromatography Data: Origins and Corrections
,”
Journal of Liquid Chromatography
, Vol.
3
, No.
11
,
1980
, pp.
1637
-
1655
.
22.
Samay
,
G.
,
Kubin
,
M.
, and
Podesva
,
J.
, “
Reliability of Universal Calibration for Calculating Molecular Weights from GPC Data
,”
Die Angewandte Makromolekulare
, Vol.
72
,
1978
, pp.
185
-
198
.
23.
Penman
,
C. S.
and
Sparrow
,
C. R.
, “
Gel Permeation Chromatography: Automation of Data Collection and Calculation
,”
Proceedings of the Institute of Petroleum, London, No. 2, Petroanalysis, '81
, pp.
291
-
299
.
24.
Vandemark
,
F. L.
and
Attebery
,
J. M.
, “
Polymer Characterization by GPC Using On-line Data Processing
,”
Chromatographic Newsletter
, Vol.
7
, No.
2
,
08
1979
, pp.
34
-
37
.
25.
McCrary
,
T. J.
, Jr.
, “
Quality Assurance Programs Via Size-Exclusion Chromatography—the WSTATISTIC Concept
,”
American Laboratory
,
01
1985
, pp.
86
-
90
.
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