Abstract

Various factors governing the detectability of explosive traces after being soaked in water were studied. The variables are: the type of the surface (surfaces liable to be found in aircraft were chosen), the type of explosive, the type of water (tap or seawater), and movement of the immersed surface in the water. The maximal immersion times (tmax) after which explosive detection was possible were evaluated. This datum was found to depend on the type of explosive (one of the important factors is solubility in water), the surface material and the environmental conditions (tap or seawater movement). Detection of PETN on high-density polyethylene, linoleum, glass and aluminum, by the chemical Explosive Testing Kit (ETK), was possible even after a month of soaking in seawater. In addition, it has been found that movement of bulk water around the samples with deposited explosives considerably decreases tmax values. It is, therefore, recommended to retrieve samples for explosive analysis as soon as possible and in areas where the currents of water is minimal.

References

1.
Mullins
J
.
Lost at sea. Seawater launders the evidence after a plane crash
.
New Scientist
1998
;
157
:19.
2.
Fox
FT
,
Sisk
S
,
DiBartolo
R
.
Immersion studies of aircraft parts exposed to plastic explosives
. Report (
U.S. Department of Transportation. Federal Aviation Administration
)
1998
;13.
3.
Yinon
J
,
Zitrin
S
.
Modern methods and applications in analysis of explosives
.
New York
:
John Wiley & Sons
1993
;
33
267
.
4.
Lewin
U
,
Efer
J
,
Engewald
W
.
High-performance liquid chromatographic analysis with electrochemical detection for residues of explosives in water samples around a former ammunition plant
.
J Chromatogr
 0021-9673
1996
;
730
:
161
7
.
5.
Welsch
T
,
Block
H
.
Separation and enrichment of traces of explosives and their by-products from water by multiple micro liquid extraction for their determination by capillary gas chromatography
.
Fresenius J Anal Chem
 0937-0633
1997
;
357
:
904
8
.
6.
Proceedings of Workshop on explosives trace analysis methods
.
DERA, Fort Halstead, Sevenoaks, Kent
, April 28–29,
1999
. In:
Science & Justice
 1355-0306
1999
;
39
:
261
8
.
7.
Sigman
ME
,
Ma
C-Yu
.
In-injection port thermal desorption for explosives trace evidence analysis
.
Anal Chem
 0003-2700 https://doi.org/10.1021/ac9901079
1999
;
71
:
4119
24
.
8.
Woltman
SJ
,
Even
WR
,
Sahlin
E
,
Weber
SG
.
Chromatographic detection of nitroaromatic and nitramine compounds by electrochemical reduction combined with photoluminescence following electron transfer
.
Anal Chem
 0003-2700
2000
;
72
:
4928
33
.
9.
Donner
DL
,
Shriver-Lake
LC
,
McCollum
A
,
Ligler
FS
.
Transition from laboratory to on-site environmental monitoring of 2,4,6-trinitrotoluene using a portable fiber optic biosensor
. In:
Aga
DS
,
Thurman
EM
, editors.
Immunochemical technology for environmental applications
.
Washington, DC
:
American Chemical Society, Symposium Series
1997
;
657
:
198
209
.
10.
Bart
JC
,
Judd
LL
,
Hoffman
KE
,
Wilkins
AM
,
Charles
PT
,
Kusterbeck
AW
.
Detection and quantitation of the explosives 2,4,6-trinitrotoluene and hexahydro-1,3,5-trinitro-1,3,5-triazine in groundwater using a continuous flow immunosensor
. In:
Aga
DS
,
Thurman
EM
, editors.
Immunochemical technology for environmental applications
.
Washington, DC
:
American Chemical Society, Symposium Series
1997
;
657
:
210
20
.
11.
Almog
J
,
Kraus
S
,
Glattstein
B
.
ETK—an operational explosive testing kit
.
J Energetic Mater
 0737-0652
1986
;
4
:
159
67
.
12.
Yinon
J
,
Zitrin
S
.
Modern methods and applications in analysis of explosives
.
New York
:
John Wiley & Sons
1993
;
1
32
.
13.
Advanced version of ETK, which detects also inorganic nitrates, chlorates and bromates, was developed by the Israel Institute for Biological Research: Margalit,Y. Kit for detecting explosives
. US Patent 5,480,612
02
01
1996
.
14.
Yinon
J
,
Zitrin
S
.
Modern methods and applications in analysis of explosives
.
New York
:
John Wiley & Sons
1993
;
170
90
.
This content is only available via PDF.
You do not currently have access to this content.