Dielectric properties of electrospun polyvinylpyrrolidone (PVP) and polyacrylonitrile (PAN) nanocomposite fibers were determined as a function of temperature and concentration in order to explore the possibility of using them as dielectric materials in different industrial applications. Multiwall carbon nanotubes and Ni0.6Zn0.4Fe2O4 (NiZn ferrite) were individually dispersed into the polymeric solutions of PVP and PAN and were then electrospun at various conditions. Thin layers of films were placed between two parallel Al electrode plates of the capacitance bridge prior to the measurements. We determined that nanoscale inclusions and temperature mainly affect the dielectric properties of the nanocomposite fibers. The dielectric studies can provide critical information for many electronic applications, such as loss of a cable insulator, the impedance of a substrate, and the frequency of a dielectric resonator.

1.
Ho
,
P. S.
,
Leu
,
J.
, and
Lee
,
W. W.
, 2003,
Low Dielectric Constant Materials for IC Application
,
Springer
,
New York
.
2.
Nalwa
,
H. S.
, 1999,
Handbook of Low and High Dielectric Constant Materials and Their Applications—Materials and Processing
, Vol.
1
,
Academic
,
New York
.
3.
Huff
,
H. R.
, and
Gilmer
,
D. C.
, 2005,
High Dielectric Constant Materials: VLSI MOSFET Application
(
Technology & Engineering
,
New York
).
4.
Asmatulu
,
R.
,
Geist
,
B.
,
Spillman
,
W.
, and
Claus
,
R. O.
, 2005, “
Dielectric Properties of Electrostatic Self-Assembled (ESA) Films
,”
Mater. Res. Soc. Symp. Proc.
0272-9172,
871E
, pp.
I9.2.1
I9.2.6
.
5.
Asmatulu
,
R.
,
Geist
,
B.
,
Spillman
,
W.
, and
Claus
,
R. O.
, 2005, “
Dielectric Constant and Breakdown Field Studies of Electrostatic Self-Assembled Materials
,”
Smart Mater. Struct.
0964-1726,
14
, pp.
1493
1500
.
6.
Asmatulu
,
R.
,
Spillman
,
W.
, and
Claus
,
R. O.
, 2005, “
Dielectric Constant Measurements of Nanoscale Thickness Polymeric Films
,”
Proc. SPIE
0277-786X,
5761
, pp.
31
39
.
7.
Ramakrishna
,
S.
, 2005,
An Introduction to Electrospinning and Nanofibers
(
World Scientific
,
Singapore
).
8.
Gogotsi
,
Y.
, 2006,
Nanomaterials Handbook
(
CRC
,
Boca Raton, FL
).
9.
Taylor
,
G.
, 1969, “
Electrically Driven Jets
,”
Proc. R. Soc. London, Ser. A
0950-1207,
313
, pp.
453
475
.
10.
Reneker
,
D.
,
Yarin
,
A. H.
,
Fong
,
H.
, and
Koombhongse
,
S.
, 2000, “
Bending Instability of Electrically Charged; Liquid Jets of Polymer Solutions in Electrospinning
,”
J. Appl. Phys.
0021-8979,
87
, pp.
4531
4557
.
11.
Yarin
,
A. H.
,
Koombhongse
,
S.
, and
Reneker
,
D.
, 2001, “
Bending Instability in Electrospinning of Nanofibers
,”
J. Appl. Phys.
0021-8979,
89
, pp.
3018
3026
.
12.
Hohman
,
M. M.
,
Shin
,
M.
,
Rutledge
,
G.
, and
Brenner
,
M. P.
, 2001, “
Electrospinning and Electric Forced Jets: I. Stability Theory
,”
Phys. Fluids
1070-6631,
13
, pp.
2201
2220
.
13.
Kalayci
,
V. E.
,
Patra
,
P. K.
,
Buer
,
A.
,
Ugbolue
,
S. C.
,
Kim
,
Y. K.
, and
Warner
,
S. B.
, 2004, “
Fundamental Investigations on Electrospun Fibers
,”
J. Adv. Mater.
1070-9789,
36
(
4
), pp.
43
47
.
14.
Rutledge
,
G. C.
,
Shin
,
M. Y.
,
Warner
,
S. B.
,
Grimler
,
M.
, and
Ugbolue
,
S. C.
, 2001, “
Fundamental Investigation of the Formation and Properties of Electrospun Fibers
,” National Textile Center Annual Report, Report No. M98-D01.
15.
Gupta
,
P.
,
Asmatulu
,
R.
,
Wilkes
,
G.
, and
Claus
,
R. O.
, 2006, “
Superparamagnetic Flexible Substrates Based on Submicron Electrospun Estane® Fibers Containing MnZnFe–Ni Nanoparticles
,”
J. Appl. Polym. Sci.
0021-8995,
100
, pp.
4935
4942
.
16.
Gupta
,
P.
,
Asmatulu
,
R.
,
Claus
,
R.
, and
Wilkes
,
G.
, 2005, “
Superparamagnetic Flexible Substrates Based on Submicron Electrospun Estane® Fibers Containing MnZnFe–Ni Nanoparticles
,”
Mater. Res. Soc. Symp. Proc.
0272-9172,
877E
, pp.
S5.7.1
S5.7.6
.
17.
Dzenis
,
Y.
, 2008, “
Structural Nanocomposites
,”
Science
0036-8075,
319
, pp.
419
420
.
18.
Buschow
,
K. H. J.
, 2006,
Handbook of Magnetic Materials
, Vol.
16
,
Elsevier
,
New York
.
19.
Omar
,
M. A.
, and
Ross
,
G. F.
, 1993,
Elementary Solid State Physics: Principles and Applications
,
Addison Wesley
,
New York
.
20.
Sattar
,
A. A.
,
El-Sayed
,
H. M.
,
El-Shokrofy
,
K. M.
, and
El-Tabey
,
M. M.
, 2007, “
Study of the dc Resistivity and Thermoelectric Power in Mn-Substituted Ni–Zn Ferrites
,”
J. Mater. Sci.
0022-2461,
42
, pp.
149
155
.
21.
Lagarkov
,
A. N.
,
Matytsin
,
S. M.
,
Rozanov
,
K. N.
, and
Sarychev
,
A. K.
, 1998, “
Dielectric Properties of Fiber-Filled Composites
,”
J. Appl. Phys.
0021-8979,
84
, pp.
3806
3814
.
22.
Dang
,
Z.
,
Shen
,
Y.
,
Fan
,
L.
,
Cai
,
N.
, and
Nan
,
C.
, 2003, “
Dielectric Properties of Carbon Fiber Filled Low-Density Polyethylene
,”
J. Appl. Phys.
0021-8979,
93
, pp.
5543
5545
.
23.
Niklasson
,
G. A.
, and
Nettelblad
,
B.
, 2002,
Sixth International Conference on Dielectric Properties of Porous Materials
,
Manchester, UK
,
IEEE
,
New York
, pp.
450
453
.
24.
Maex
,
K.
,
Baklanov
,
M. R.
,
Shamiryan
,
D.
, and
Lacopi
,
F.
, 2003, “
Low Dielectric Constant Materials for Microelectronics
,”
J. Appl. Phys.
0021-8979,
93
, pp.
8793
8841
.
You do not currently have access to this content.